Synthesis of perfluoroalkyl gelators and their selective gelation ability for fluorinated solvents1

Toshiaki Shimasaki, Yuki Ohno, Mao Tanaka, Masato Amano, Yuta Sasaki, Hirobumi Shibata, Motonori Watanabe, Naozumi Teramoto, Mitsuhiro Shibata

    研究成果: ジャーナルへの寄稿学術誌査読

    3 被引用数 (Scopus)

    抄録

    Novel perfluoroalkyl gelators without hydrogen bondsbis(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) iso-phthalate (1m), bis(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadeca-fluorooctyl) terephthalate (1p), and tris-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) benzene-1,3,5-tricarboxylate (2)were synthesized. Their molecular structures were investigated by density functional theory calculations at the B3LYP/cc-pVDZ level. The gelation abilities of 1m, 1p, and 2 were examined and compared to their normal octyl homologues 1m¤, 1p¤, and 2¤. None of the gelators could be gelated in common organic solvents, but gelated well in fluorinated solvents.

    本文言語英語
    ページ(範囲)97-104
    ページ数8
    ジャーナルBulletin of the Chemical Society of Japan
    92
    1
    DOI
    出版ステータス出版済み - 2019

    !!!All Science Journal Classification (ASJC) codes

    • 化学 (全般)

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