抄録
Various pH-responsive polymers with amino groups were synthesized via living cationic polymerization of vinyl ethers in the presence of an added base. The synthesis starts with living cationic polymerization of 2-vinyloxyethyl phthalimide (PIVE) in CH2Cl2 in the presence of 1,4-dioxane at 0°C. The base-stabilized living system yields nearly monodispersed polymers (Mw/Mn < 1.1), which have never been obtained using other initiating systems. The deprotection of the pendant phthalimide groups gave well-defined pH-responsive polymers with pendant amino groups. In addition, various pH-responsive diblock copolymers and star-shaped polymers were also prepared.
本文言語 | 英語 |
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ページ数 | 1 |
出版ステータス | 出版済み - 10月 18 2006 |
外部発表 | はい |
イベント | 55th SPSJ Annual Meeting - Nagoya, 日本 継続期間: 5月 24 2006 → 5月 26 2006 |
その他
その他 | 55th SPSJ Annual Meeting |
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国/地域 | 日本 |
City | Nagoya |
Period | 5/24/06 → 5/26/06 |
!!!All Science Journal Classification (ASJC) codes
- 工学(全般)