Synthesis of photochromic nanoparticles and determination of the mechanism of photochromism

Shuhei Inoue, Takahiro Kawamoto, Yukihiko Matsumura, Kentaro Tomita, Kiichiro Uchino, Keiji Takata, Hiroshi Kajiyama

研究成果: Contribution to journalArticle査読

9 被引用数 (Scopus)

抄録

Photochromic nanoparticles of zinc-silicon oxide were synthesized using plasma enhanced chemical vapor deposition. These particles turned black upon irradiating with ultraviolet light. We investigated this phenomenon using density functional theory calculations. Silicon inclusions create trap levels and oxygen defects that reduce the ionization potential of ZnO. This forms a quantum potential between ZnO and zinc-silicon oxide, and the excited electron is stable. Because oxygen defects also increase the bond overlap population between the zinc atoms in a ZnO crystal, they introduce further defects and help in the formation of quantum potentials. Growth of a perfect crystal of ZnO prevents the formation of oxygen defects, which is not desirable for photochromism.

本文言語英語
論文番号055214
ジャーナルAIP Advances
6
5
DOI
出版ステータス出版済み - 5 1 2016

All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)

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