TY - JOUR
T1 - Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups
AU - Mutoh, Mai
AU - Sudoh, Keisuke
AU - Furukawa, Ko
AU - Minoura, Mao
AU - Nakano, Haruyuki
AU - Matano, Yoshihiro
N1 - Funding Information:
This work was supported by JSPS KAKENHI (Grant Number: 18H01961 to YM, 15K05392 and 18K05036 to HN). We would like to express our gratitude to the SPring-8 synchrotron, where synchrotron radiation experiments were performed at the BL40XU beamline with the approval of the Japan Synchrotron Radiation Research Institute (JASRI) (proposals 2018A1405 and 2018B1275).
Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Copyright:
Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2019/3
Y1 - 2019/3
N2 - Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.
AB - Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.
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U2 - 10.1002/ajoc.201900085
DO - 10.1002/ajoc.201900085
M3 - Article
AN - SCOPUS:85061919563
VL - 8
SP - 352
EP - 355
JO - Asian Journal of Organic Chemistry
JF - Asian Journal of Organic Chemistry
SN - 2193-5807
IS - 3
ER -