Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N-Alkyl Groups

Mai Mutoh, Keisuke Sudoh, Ko Furukawa, Mao Minoura, Haruyuki Nakano, Yoshihiro Matano

研究成果: ジャーナルへの寄稿学術誌査読

14 被引用数 (Scopus)

抄録

Nickel(II) and copper(II) complexes of redox-switchable 20π, 19π, and 18π 5,15-dialkyl-10,20-diaryl-5,15-diazaporphyrins were prepared through a metal-templated cyclization method. Furthermore, the terminal silyloxy groups in the peripheral N-alkyl chains were transformed into hydroxy groups by deprotection. It is worth noting that redox reactions between the 19π and 18π systems bearing hydroxy groups caused a change in the water solubility of the diazaporphyrin chromophore.

本文言語英語
ページ(範囲)352-355
ページ数4
ジャーナルAsian Journal of Organic Chemistry
8
3
DOI
出版ステータス出版済み - 3月 2019

!!!All Science Journal Classification (ASJC) codes

  • 有機化学

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