Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

Yoshifumi Amamoto, Yuji Higaki, Hideyuki Otsuka, Atsushi Takahara

研究成果: 会議への寄与タイプ学会誌査読

抄録

Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.

本文言語英語
ページ数1
出版ステータス出版済み - 10月 18 2006
イベント55th SPSJ Annual Meeting - Nagoya, 日本
継続期間: 5月 24 20065月 26 2006

その他

その他55th SPSJ Annual Meeting
国/地域日本
CityNagoya
Period5/24/065/26/06

!!!All Science Journal Classification (ASJC) codes

  • 工学(全般)

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