Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

Yoshifumi Amamoto; Yuji Higaki; Hideyuki Otsuka; Atsushi Takahara

Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

Yoshifumi Amamoto, Yuji Higaki, Hideyuki Otsuka, Atsushi Takahara

分子集積化学部門

研究成果: 会議への寄与タイプ › 学会誌 › 査読

抄録

Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.

本文言語	英語
ページ数	1
出版ステータス	出版済み - 10月 18 2006
イベント	55th SPSJ Annual Meeting - Nagoya, 日本継続期間: 5月 24 2006 → 5月 26 2006

その他

その他	55th SPSJ Annual Meeting
国/地域	日本
City	Nagoya
Period	5/24/06 → 5/26/06

!!!All Science Journal Classification (ASJC) codes

工学（全般）

他のファイルとリンク

引用スタイル

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title = "Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties",

abstract = "Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.",

author = "Yoshifumi Amamoto and Yuji Higaki and Hideyuki Otsuka and Atsushi Takahara",

year = "2006",

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note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

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T1 - Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

AU - Amamoto, Yoshifumi

AU - Higaki, Yuji

AU - Otsuka, Hideyuki

AU - Takahara, Atsushi

PY - 2006/10/18

Y1 - 2006/10/18

N2 - Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.

AB - Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.

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M3 - Paper

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T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

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その他

!!!All Science Journal Classification (ASJC) codes

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