Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties

Yoshifumi Amamoto, Yuji Higaki, Hideyuki Otsuka, Atsushi Takahara

研究成果: 会議への寄与タイプ論文

抄録

Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.

元の言語英語
ページ数1
出版物ステータス出版済み - 10 18 2006
イベント55th SPSJ Annual Meeting - Nagoya, 日本
継続期間: 5 24 20065 26 2006

その他

その他55th SPSJ Annual Meeting
日本
Nagoya
期間5/24/065/26/06

Fingerprint

Stars
Molecular weight
Atom transfer radical polymerization
Polydispersity
Polymers
Polymethyl methacrylates
Block copolymers
Esters
Copolymers
Heating

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Amamoto, Y., Higaki, Y., Otsuka, H., & Takahara, A. (2006). Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties. 論文発表場所 55th SPSJ Annual Meeting, Nagoya, 日本.

Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties. / Amamoto, Yoshifumi; Higaki, Yuji; Otsuka, Hideyuki; Takahara, Atsushi.

2006. 論文発表場所 55th SPSJ Annual Meeting, Nagoya, 日本.

研究成果: 会議への寄与タイプ論文

Amamoto, Y, Higaki, Y, Otsuka, H & Takahara, A 2006, 'Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties' 論文発表場所 55th SPSJ Annual Meeting, Nagoya, 日本, 5/24/06 - 5/26/06, .
Amamoto Y, Higaki Y, Otsuka H, Takahara A. Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties. 2006. 論文発表場所 55th SPSJ Annual Meeting, Nagoya, 日本.
Amamoto, Yoshifumi ; Higaki, Yuji ; Otsuka, Hideyuki ; Takahara, Atsushi. / Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties. 論文発表場所 55th SPSJ Annual Meeting, Nagoya, 日本.1 p.
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