抄録
Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.
| 元の言語 | 英語 |
|---|---|
| ページ数 | 1 |
| 出版物ステータス | 出版済み - 10 18 2006 |
| イベント | 55th SPSJ Annual Meeting - Nagoya, 日本 継続期間: 5 24 2006 → 5 26 2006 |
その他
| その他 | 55th SPSJ Annual Meeting |
|---|---|
| 国 | 日本 |
| 市 | Nagoya |
| 期間 | 5/24/06 → 5/26/06 |
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All Science Journal Classification (ASJC) codes
- Engineering(all)
これを引用
Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties. / Amamoto, Yoshifumi; Higaki, Yuji; Otsuka, Hideyuki; Takahara, Atsushi.
2006. 論文発表場所 55th SPSJ Annual Meeting, Nagoya, 日本.研究成果: 会議への寄与タイプ › 論文
}
TY - CONF
T1 - Synthesis of star polymers via radical crossover reaction of alkoxyamine moieties
AU - Amamoto, Yoshifumi
AU - Higaki, Yuji
AU - Otsuka, Hideyuki
AU - Takahara, Atsushi
PY - 2006/10/18
Y1 - 2006/10/18
N2 - Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.
AB - Block copolymers which consist of poly(methyl methacrylate) and random copolymer of methyl methacrylate and methacrylic esters with alkoxyamine moiety (1) were prepared by ATRP technique and polymers with controlled molecular weight were obtained. By heating degassed anisole solution of 1 at 100°C, localized cross-linking reaction occurred as a result of radical crossover reaction of alkoxyamine moieties to form multi-armed architecture. Molecular weight and polydispersity at equilibrium state strongly depended on the primary structure of 1.
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UR - http://www.scopus.com/inward/citedby.url?scp=33749682819&partnerID=8YFLogxK
M3 - Paper
ER -