Synthesis of substituted azulenes via Pt(II)-Catalyzed ring-expanding cycloisomerization

Kazuteru Usui, Kensuke Tanoue, Kosuke Yamamoto, Takashi Shimizu, Hiroshi Suemune

研究成果: ジャーナルへの寄稿記事

18 引用 (Scopus)

抜粋

Substituted azulenes, valuable structures for electronic devices and pharmaceuticals, have been synthesized by the platinum(II)-catalyzed intramolecular ring-expanding cycloisomerization of 1-en-3-yne with ortho-disubstituted benzene. This novel method provides an alternative route for the efficient synthesis of substituted azulenes. The reaction mechanism of selected catalytic transformations was explored using density functional calculations.

元の言語英語
ページ(範囲)4662-4665
ページ数4
ジャーナルOrganic Letters
16
発行部数17
DOI
出版物ステータス出版済み - 9 5 2014

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

Usui, K., Tanoue, K., Yamamoto, K., Shimizu, T., & Suemune, H. (2014). Synthesis of substituted azulenes via Pt(II)-Catalyzed ring-expanding cycloisomerization. Organic Letters, 16(17), 4662-4665. https://doi.org/10.1021/ol502270q