Synthesis of Ynolates via Double Deprotonation of Nonbrominated Esters

Jun Sun, Toshiya Yoshiiwa, Takayuki Iwata, Mitsuru Shindo

研究成果: ジャーナルへの寄稿記事

抄録

Herein, we report a double deprotonation method used for the preparation of ynolates starting from nonbrominated 2,6-di-tert-butylphenyl esters. The current method is superior to the previously described double lithium/halogen exchange approach because easily accessible starting materials are used. This method will be especially useful for preparation of ynolates bearing functional groups in organic synthesis.

元の言語英語
ページ(範囲)6585-6588
ページ数4
ジャーナルOrganic Letters
21
発行部数17
DOI
出版物ステータス出版済み - 9 6 2019

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Bearings (structural)
Deprotonation
Halogens
Lithium
Functional groups
esters
Esters
preparation
synthesis
halogens
Synthetic Chemistry Techniques
lithium

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

Synthesis of Ynolates via Double Deprotonation of Nonbrominated Esters. / Sun, Jun; Yoshiiwa, Toshiya; Iwata, Takayuki; Shindo, Mitsuru.

:: Organic Letters, 巻 21, 番号 17, 06.09.2019, p. 6585-6588.

研究成果: ジャーナルへの寄稿記事

Sun, Jun ; Yoshiiwa, Toshiya ; Iwata, Takayuki ; Shindo, Mitsuru. / Synthesis of Ynolates via Double Deprotonation of Nonbrominated Esters. :: Organic Letters. 2019 ; 巻 21, 番号 17. pp. 6585-6588.
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