Synthesis of zeolite from coal fly ashes with different silica-alumina composition

Miki Inada, Yukari Eguchi, Naoya Enomoto, Junichi Hojo

研究成果: Contribution to journalArticle査読

193 被引用数 (Scopus)

抄録

Coal fly ashes can be converted into zeolites by hydrothermal alkaline treatment. This study focuses on the effect of Si/Al molar ratio of the fly ash source on the type of formed zeolite, which also is affected by the alkaline condition. The fly ashes were mixed with an aqueous NaOH solution and hydrothermally treated at about 100°C. Zeolite Na-Pl and/or hydroxy-sodalite appeared after the treatment. Zeolite Na-Pl predominantly formed from silica-rich fly ash at a low-NaOH concentration. The cation exchange capacity of the product with a large content of zeolite Na-Pl reached a value of 300 meq/100 g. The type of the product was controlled by addition of aerosil silica or alumina. It was found that silica addition effectively enhances the formation of zeolite Na-Pl, even at a high-NaOH concentration. These results were discussed on the basis of a formation mechanism of zeolite from coal fly ash through dissolution-precipitation process.

本文言語英語
ページ(範囲)299-304
ページ数6
ジャーナルFuel
84
2-3
DOI
出版ステータス出版済み - 1 2005

All Science Journal Classification (ASJC) codes

  • 化学工学(全般)
  • 燃料技術
  • エネルギー工学および電力技術
  • 有機化学

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