Synthesis of zero-valent iron nanoparticles via laser ablation in a formate ionic liquid under atmospheric conditions

Shinya Okazoe, Yoshiro Yasaka, Masaki Kudo, Hiroshi Maeno, Yasukazu Murakami, Yoshifumi Kimura

研究成果: Contribution to journalArticle

4 引用 (Scopus)

抜粋

Transition metal nanoparticles (NPs) are promising materials for use as catalysts in many processes, although they are easily oxidized under ambient conditions. In this communication, a novel synthetic method is proposed for producing zero-valent iron (Fe) NPs by laser ablation under atmospheric conditions using the reducing properties of a formate-based ionic liquid solvent. The valence state of Fe was confirmed using X-ray absorption near edge structure (XANES) spectroscopy. The Fe NPs adopt a face centered cubic structure after synthesis, which gradually transforms to a body centered cubic structure after one month. The method can be extended to the synthesis of other transition metal NPs that are easily oxidized.

元の言語英語
ページ(範囲)7834-7837
ページ数4
ジャーナルChemical Communications
54
発行部数56
DOI
出版物ステータス出版済み - 2018

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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