Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexane-diamine; MIII = Fe, Co)

Nobuo Fukita, Masaaki Ohba, Hisashi Okawa

研究成果: ジャーナルへの寄稿Conference article

6 引用 (Scopus)

抜粋

A new type of cyanide-bridged bimetallic assemblies, [Ni(chxn)2]3[M(CN)6]2·2H2O (chxn = 1,2-trans-cyclohexanediamine; M3+ = Fe (1), Co (2)), have been prepared. The X-ray crystallography for the assemblies has proved a 2-D network comprised of M6Ni6 dodecagon units extended by M-CN-Ni linkage. Compound 1 shows a ferromagnetic spin-exchange interaction between the adjacent Fe(III) and Ni(II) ions through cyanide bridge and a long-range magnetic ordering below 13.1 K.

元の言語英語
ページ(範囲)217-224
ページ数8
ジャーナルMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
342
DOI
出版物ステータス出版済み - 1 1 2000
イベントProceedings of the International Symposium Molecular Design and Funtionalities of Assambled Metal Complexes (AMS'99) - Kyoto, Jpn
継続期間: 11 30 199912 2 1999

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics

フィンガープリント Synthesis, structure and magnetism of new bimetallic assemblies, [Ni(chxn)<sub>2</sub>]<sub>3</sub>[M(CN)<sub>6</sub>]<sub>2</sub>·2H<sub>2</sub>O (chxn = 1,2-trans-cyclohexane-diamine; M<sup>III</sup> = Fe, Co)' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用