Synthesis, structure and properties of novel homochiral metal-organic coordination polymers

Wan Chen, Sheng Qun Su, Shu Yan Song, Xue Zhi Song, Hong Jie Zhang

研究成果: ジャーナルへの寄稿学術誌査読

11 被引用数 (Scopus)

抄録

Two new homochiral metal-organic coordination polymers[M(D-cam)(H 2mbdpz)] n[M=Zn(complex 1), Co(complex 2); D-H 2cam=D-(+)-camphoric acid, H 2mbdpz=4, 4'-methylenebis(3, 5-dime-{thylpyrazole})] were prepared by mixing ligands with corresponding transition metal ions under hydrothermal conditions. The complexes were characterized by means of single-crystal X-ray diffraction, elemental analysis, thermograrimetri analysis(TGA), powder X-ray diffraction(XRD) and photoluminescent(PL) spectrometry. X-ray crystallography reveals that complexes 1 and 2 are isomorphous and homochiral, exhibiting the three-dimensional open structure with a ThSi 2 type of uninodal 3-connected networks.

本文言語英語
ページ(範囲)215-218
ページ数4
ジャーナルGaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
33
2
DOI
出版ステータス出版済み - 2月 2012
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)

フィンガープリント

「Synthesis, structure and properties of novel homochiral metal-organic coordination polymers」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル