@article{a0104ae046b84198b5a3aeffa46ff572,
title = "Synthetic study of ciguatoxin. Absolute configuration of the C2 hydroxy group",
abstract = "The absolute stereochemistry of the secondary alcohol of the 1,2-dihydroxybutenyl substituent of ciguatoxin (1) was shown to be S by comparing (he split CD curve of ciguatoxin tetra-p-bromobenzoate (2) with those of di- and tri-p-bromobenzoates of AB ring fragments that were synthesized enaotioselectively.",
author = "Hiroki Oguri and Shojiro Hishiyama and Ohki Sato and Tohru Oishi and Masahiro Hirama and Michio Murata and Takeshi Yasumoto and Nabuyuki Harada",
note = "Funding Information: We thank Dr. Masayuki Satake for his helpful discussions and measurement of Electrospray MS spectra. NMR (500 MHz and 600 MHz), MS, and elemental analyses were performed by the Instrumental Analysis Center for Chemistry, Faculty of Science, Tohoku University. A fellowship to H. O. from the Japanese Society for the Promotion of Science for Young Japanese Scientists is gratefully acknowledged. This work was supported in part by the Ministry of Education, Science, Sports, and Culture of Japan.",
year = "1997",
month = mar,
day = "3",
doi = "10.1016/S0040-4020(97)00071-9",
language = "English",
volume = "53",
pages = "3057--3072",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "9",
}