Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites

Masaki Azuma, Yuki Sakai, Takumi Nishikubo, Masaichiro Mizumaki, Tetsu Watanuki, Takashi Mizokawa, Kengo Oka, Hajime Hojo, Makoto Naka

研究成果: Contribution to journalReview article

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Charge distribution changes in Bi- and Pb-3d transition metal perovskite type oxides were examined by comprehensive precise structural analysis, spectroscopy, and theoretical investigations. The change in the depth of the d level of the transition metal caused the intermetallic charge transfer. A temperature-induced charge-transfer transition in chemically modified BiNiO3 results in technologically important negative thermal expansion.

元の言語英語
ページ(範囲)1371-1377
ページ数7
ジャーナルDalton Transactions
47
発行部数5
DOI
出版物ステータス出版済み - 1 1 2018

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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    Azuma, M., Sakai, Y., Nishikubo, T., Mizumaki, M., Watanuki, T., Mizokawa, T., Oka, K., Hojo, H., & Naka, M. (2018). Systematic charge distribution changes in Bi- and Pb-3d transition metal perovskites. Dalton Transactions, 47(5), 1371-1377. https://doi.org/10.1039/c7dt03244g