TY - JOUR
T1 - Tailor-making of desired assemblies from well-designed monomers
T2 - Use of calix[4]arene conformers as building blocks
AU - Arimori, Susumu
AU - Nagasaki, Takes Hi
AU - Shinkai, Seiji
PY - 1993
Y1 - 1993
N2 - Water-soluble, conformationally-immobilized calix[4]arenes with cone and 1,3-alternate conformations (cone-1 and 1,3-alternate-1, respectively) have been synthesized. In aqueous solution cone-1. with a cone-shaped surface, aggregated into micelles with 20-40 A diameter whereas 1,3-alternate-1, with a cylindrical surface, could not form such aggregates for concentrations up to 0.010 mol dm-3.
AB - Water-soluble, conformationally-immobilized calix[4]arenes with cone and 1,3-alternate conformations (cone-1 and 1,3-alternate-1, respectively) have been synthesized. In aqueous solution cone-1. with a cone-shaped surface, aggregated into micelles with 20-40 A diameter whereas 1,3-alternate-1, with a cylindrical surface, could not form such aggregates for concentrations up to 0.010 mol dm-3.
UR - http://www.scopus.com/inward/record.url?scp=37049087865&partnerID=8YFLogxK
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U2 - 10.1039/p19930000887
DO - 10.1039/p19930000887
M3 - Article
AN - SCOPUS:37049087865
SP - 887
EP - 889
JO - Journal of the Chemical Society, Perkin Transactions 2
JF - Journal of the Chemical Society, Perkin Transactions 2
SN - 1472-7781
IS - 8
ER -