The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

Mitsuru Shindo; Kenji Matsumoto; Seiji Mori; Kozo Shishido

doi:10.1021/ja026275r

The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

Mitsuru Shindo, Kenji Matsumoto, Seiji Mori, Kozo Shishido

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

80 被引用数 (Scopus)

抄録

We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.

本文言語	英語
ページ（範囲）	6840-6841
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	124
号	24
DOI	https://doi.org/10.1021/ja026275r
出版ステータス	出版済み - 6月 19 2002
外部発表	はい

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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title = "The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes",

abstract = "We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-{\ss}-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.",

author = "Mitsuru Shindo and Kenji Matsumoto and Seiji Mori and Kozo Shishido",

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AU - Shindo, Mitsuru

AU - Matsumoto, Kenji

AU - Mori, Seiji

AU - Shishido, Kozo

PY - 2002/6/19

Y1 - 2002/6/19

N2 - We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.

AB - We have developed the first general method for a stereoselective olefination of acylsilanes via ynolate anions to produce (Z)-ß-silyl-α,β-unsaturated ester, which leads to tri- and tetrasubstituted alkenes.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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The first general method for Z-selective olefination of acylsilanes via ynolate anions providing multisubstituted alkenes

抄録

!!!All Science Journal Classification (ASJC) codes

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