The first synthesis of meso-dicycloalkylporphycenes: ring strain effects on structural and optical properties of isomeric porphyrins

Toshikazu Ono, Daiki Koga, Kenji Yoza, Yoshio Hisaeda

研究成果: Contribution to journalArticle査読

抄録

Two novel meso-dicycloalkylporphycenes, namely meso-dicyclopentyl- (Cy5Pc) and meso-dicyclohexylporphycenes (Cy6Pc) are synthesized for the first time in porphycene chemistry. We use intermolecular oxidative coupling of 5,6-dicycloalkydipyrroethenes mediated by hypervalent iodine(iii) reagents. The solution fluorescence maxima of Cy5Pc are more than 400 times as intense as that of Cy6Pc. The results suggested that photoluminescence switching is achieved through the ring strain perturbation of the meso-substituted cycloalkyl groups on the porphycene cavity.

本文言語英語
ページ(範囲)12258-12261
ページ数4
ジャーナルChemical Communications
53
91
DOI
出版ステータス出版済み - 11 14 2017

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