The first transition metal phthalocyanines: Sensitizing rubrene emission based on triplet-triplet annihilation

Jianlei Han; Fei Zhang; Jing You; Yonemura Hiroaki; Sunao Yamada; Toru Morifuji; Shirong Wang; Xianggao Li

doi:10.1039/c6pp00464d

The first transition metal phthalocyanines: Sensitizing rubrene emission based on triplet-triplet annihilation

Jianlei Han, Fei Zhang, Jing You, Yonemura Hiroaki, Sunao Yamada, Toru Morifuji, Shirong Wang, Xianggao Li

研究成果: Contribution to journal › Article › 査読

4 被引用数 (Scopus)

抄録

Metallophthalocyanines (MPc-o-Cou, M = Fe, Co, Ni, and Cu) with fourth period metal ions have been successfully applied as a sensitizer coupled with rubrene (Rub) in photon upconversion based on triplet-triplet annihilation. An upconversion quantum yield (φ_PUC) of up to 4.82% was observed in the CoPc-o-Cou:Rub couple. The absorption and phosphorescence emission spectra showed that the Q bands and phosphorescence emission peaks were dramatically dependent on the number of d-electrons of the metal ions in MPc-o-Cou. These results suggested that the photon upconversion behavior of MPc-o-Cou:Rub systems could be managed by altering the metal ions in MPc-o-Cou.

本文言語	英語
ページ（範囲）	1384-1390
ページ数	7
ジャーナル	Photochemical and Photobiological Sciences
巻	16
号	9
DOI	https://doi.org/10.1039/c6pp00464d
出版ステータス	出版済み - 2017

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

文献へのアクセス

10.1039/c6pp00464d

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引用スタイル

The first transition metal phthalocyanines : Sensitizing rubrene emission based on triplet-triplet annihilation. / Han, Jianlei; Zhang, Fei; You, Jing; Hiroaki, Yonemura; Yamada, Sunao; Morifuji, Toru; Wang, Shirong; Li, Xianggao.

In: Photochemical and Photobiological Sciences, Vol. 16, No. 9, 2017, p. 1384-1390.

研究成果: Contribution to journal › Article › 査読

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abstract = "Metallophthalocyanines (MPc-o-Cou, M = Fe, Co, Ni, and Cu) with fourth period metal ions have been successfully applied as a sensitizer coupled with rubrene (Rub) in photon upconversion based on triplet-triplet annihilation. An upconversion quantum yield (φPUC) of up to 4.82% was observed in the CoPc-o-Cou:Rub couple. The absorption and phosphorescence emission spectra showed that the Q bands and phosphorescence emission peaks were dramatically dependent on the number of d-electrons of the metal ions in MPc-o-Cou. These results suggested that the photon upconversion behavior of MPc-o-Cou:Rub systems could be managed by altering the metal ions in MPc-o-Cou.",

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AU - Han, Jianlei

AU - Zhang, Fei

AU - You, Jing

AU - Hiroaki, Yonemura

AU - Yamada, Sunao

AU - Morifuji, Toru

AU - Wang, Shirong

AU - Li, Xianggao

PY - 2017

Y1 - 2017

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