Theoretical study of thermal isomerization of silacyclobutene to cyclopropene

Yoshihito Shiota, Makoto Yasunaga, Akinobu Naka, Mitsuo Ishikawa, Kazunari Yoshizawa

研究成果: ジャーナルへの寄稿記事

13 引用 (Scopus)

抜粋

The reaction pathway and energetics for the conversion of silacyclobutene to cyclopropene was investigated. IRC calculations were performed to trace the 1,2-siloxyl shift in this mechanism. Cyclopropene was obtained experimentally by the thermal isomerization of silacylobutene and by the subsequent trapping of cyclopropane using tert-butyl alcohol. The IRC calculations indicate that the 1,2-siloxyl shift can be divided into two processes: 1,2-siloxyl shift and the formation of the cyclopropene ring.

元の言語英語
ページ(範囲)4744-4749
ページ数6
ジャーナルOrganometallics
23
発行部数20
DOI
出版物ステータス出版済み - 9 27 2004

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

フィンガープリント Theoretical study of thermal isomerization of silacyclobutene to cyclopropene' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用