Theoretical study on the conformation and aromaticity of regular and singly N-confused [28]hexaphyrins

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    Structures and electronic states of regular and singly N-confused [28]hexaphyrins(1.1.1.1.1.1) were thoroughly studied with the aid of DFT calculations. To obtain systematic information, all the conceivable structures (450 structures in total) were examined. Unlike the [26]hexaphyrins(1.1.1.1.1.1) reported previously (J. Org. Chem. 2010, 75, 8213-8223), the electronic states of [28]hexaphyrins were highly affected by their conformations. The planar conformers (dumbbell, rectangular, triangular) show Hückel antiaromaticity, while the singly twisted conformers show Möbius aromaticity. Figure-eight structures correspond to the doubly twisted structures and show nonaromaticity. Disruption of annulenic circuits in singly N-confused [28]hexaphyrins caused weakening of both aromatic and antiaromatic characteristics. Relative stabilities among conformers were mainly governed by the intramolecular hydrogen bonds and secondarily affected by the steric factors. In addition, interconversion pathways among conformers were proposed on the basis of calculations on singly N-confused [28]hexaphyrins.

    本文言語英語
    ページ(範囲)9317-9327
    ページ数11
    ジャーナルJournal of Organic Chemistry
    78
    18
    DOI
    出版ステータス出版済み - 9 20 2013

    All Science Journal Classification (ASJC) codes

    • 有機化学

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