抄録
The reaction pathways for the thermal additions of disilacyclobutenes and acetylene are discussed from B3LYP density-functional-theory computations. Butadiene is more stable in energy than cyclobutene, the corresponding ring compound, whereas disilabutadiene is less stable than disilacyclobutene. From detailed analyses of the potential energy surfaces, disilabutadienes formed by thermal ring opening of disilacyclobutenes are confirmed to play a central role in the addition reactions as intermediates in a manner similar to the Diels-Alder reaction. The activation energies for the symmetry-allowed conrotatory ring opening of 1,2-disilacyclobut-3-ene, 1,1,2,2-tetramethyl-1,2-disilacyclobut-3-ene, and 3,4-benzo-1,1,2,2-tetramethyl-1,2-disilacyclobutene are 41.5, 46.7, and 61.9 kcal/mol, respectively, and the activation energies for the Diels-Alder coupling reactions with acetylene are 1-4 kcal/mol when measured from the disilabutadiene intermediates at the B3LYP/6-31G** level of theory. Therefore the ring opening should be the rate-determining step in these reactions; once the four-membered ring of disilacyclobutene is opened by heat treatment, the addition reactions should readily take place, leading to six-membered ring products. The transition state for the addition of 1,4-disila-1,3-butadiene and acetylene is symmetrical with respect to the Si-C bonds being formed, whereas those of 1,1,4,4-tetramethyl-1,4-disila-1,3-butadiene and acetylene and of 1,2-bis(dimethylsilylene)cyclohexa-3,5-diene and acetylene are not symmetrical. There are good reasons that such asymmetrical transition states occur in these Diels-Alder reactions; one is the asymmetrical frontier orbitals in the methyl-substituted disilabutadienes, and the other is just a steric effect of the methyl groups.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 4637-4645 |
| ページ数 | 9 |
| ジャーナル | Organometallics |
| 巻 | 18 |
| 発行部数 | 22 |
| DOI | |
| 出版物ステータス | 出版済み - 10 25 1999 |
| 外部発表 | Yes |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
これを引用
Thermal Addition of Disilacyclobutenes and Acetylene : A Theoretical Study on Diels-Alder Type Reactions. / Yoshizawa, Kazunari; Kang, Song Yun; Yamabe, Tokio; Naka, Akinobu; Ishikawa, Mitsuo.
：: Organometallics, 巻 18, 番号 22, 25.10.1999, p. 4637-4645.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - Thermal Addition of Disilacyclobutenes and Acetylene
T2 - A Theoretical Study on Diels-Alder Type Reactions
AU - Yoshizawa, Kazunari
AU - Kang, Song Yun
AU - Yamabe, Tokio
AU - Naka, Akinobu
AU - Ishikawa, Mitsuo
PY - 1999/10/25
Y1 - 1999/10/25
N2 - The reaction pathways for the thermal additions of disilacyclobutenes and acetylene are discussed from B3LYP density-functional-theory computations. Butadiene is more stable in energy than cyclobutene, the corresponding ring compound, whereas disilabutadiene is less stable than disilacyclobutene. From detailed analyses of the potential energy surfaces, disilabutadienes formed by thermal ring opening of disilacyclobutenes are confirmed to play a central role in the addition reactions as intermediates in a manner similar to the Diels-Alder reaction. The activation energies for the symmetry-allowed conrotatory ring opening of 1,2-disilacyclobut-3-ene, 1,1,2,2-tetramethyl-1,2-disilacyclobut-3-ene, and 3,4-benzo-1,1,2,2-tetramethyl-1,2-disilacyclobutene are 41.5, 46.7, and 61.9 kcal/mol, respectively, and the activation energies for the Diels-Alder coupling reactions with acetylene are 1-4 kcal/mol when measured from the disilabutadiene intermediates at the B3LYP/6-31G** level of theory. Therefore the ring opening should be the rate-determining step in these reactions; once the four-membered ring of disilacyclobutene is opened by heat treatment, the addition reactions should readily take place, leading to six-membered ring products. The transition state for the addition of 1,4-disila-1,3-butadiene and acetylene is symmetrical with respect to the Si-C bonds being formed, whereas those of 1,1,4,4-tetramethyl-1,4-disila-1,3-butadiene and acetylene and of 1,2-bis(dimethylsilylene)cyclohexa-3,5-diene and acetylene are not symmetrical. There are good reasons that such asymmetrical transition states occur in these Diels-Alder reactions; one is the asymmetrical frontier orbitals in the methyl-substituted disilabutadienes, and the other is just a steric effect of the methyl groups.
AB - The reaction pathways for the thermal additions of disilacyclobutenes and acetylene are discussed from B3LYP density-functional-theory computations. Butadiene is more stable in energy than cyclobutene, the corresponding ring compound, whereas disilabutadiene is less stable than disilacyclobutene. From detailed analyses of the potential energy surfaces, disilabutadienes formed by thermal ring opening of disilacyclobutenes are confirmed to play a central role in the addition reactions as intermediates in a manner similar to the Diels-Alder reaction. The activation energies for the symmetry-allowed conrotatory ring opening of 1,2-disilacyclobut-3-ene, 1,1,2,2-tetramethyl-1,2-disilacyclobut-3-ene, and 3,4-benzo-1,1,2,2-tetramethyl-1,2-disilacyclobutene are 41.5, 46.7, and 61.9 kcal/mol, respectively, and the activation energies for the Diels-Alder coupling reactions with acetylene are 1-4 kcal/mol when measured from the disilabutadiene intermediates at the B3LYP/6-31G** level of theory. Therefore the ring opening should be the rate-determining step in these reactions; once the four-membered ring of disilacyclobutene is opened by heat treatment, the addition reactions should readily take place, leading to six-membered ring products. The transition state for the addition of 1,4-disila-1,3-butadiene and acetylene is symmetrical with respect to the Si-C bonds being formed, whereas those of 1,1,4,4-tetramethyl-1,4-disila-1,3-butadiene and acetylene and of 1,2-bis(dimethylsilylene)cyclohexa-3,5-diene and acetylene are not symmetrical. There are good reasons that such asymmetrical transition states occur in these Diels-Alder reactions; one is the asymmetrical frontier orbitals in the methyl-substituted disilabutadienes, and the other is just a steric effect of the methyl groups.
UR - http://www.scopus.com/inward/record.url?scp=0001585499&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001585499&partnerID=8YFLogxK
U2 - 10.1021/om990316j
DO - 10.1021/om990316j
M3 - Article
AN - SCOPUS:0001585499
VL - 18
SP - 4637
EP - 4645
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 22
ER -