Thermodynamic standardization for highly photoreactive LB films made from amide derivative of p-phenylenediacrylic acid

H. R. Hafiz, Kaoru Tamada, F. Nakanishi

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

The thermodynamic concept was introduced in order to elucidate the dynamic flexibility of the amide derivative of p-phenylenediacrylic acid "1" for the formation of its monolayer. The phase transition region appeared in the surface pressure - area isotherms was interpreted in terms of molecular comformational changes between two extreme forms; bent comformation and erect comformation. The LB films prepared at higher temperatures possessed highly oriented and closely packed molecular assembly, as revealed by means of spectroscopy. Even though, the LB films prepared at lower temperatures exhibited a higher photoreactivity.

本文言語英語
ページ(範囲)123-128
ページ数6
ジャーナルMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
322
DOI
出版ステータス出版済み - 1 1 1998
外部発表はい

All Science Journal Classification (ASJC) codes

  • 凝縮系物理学

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