Thermodynamic studies on adsorption at interfaces. III. Sodium dodecyl sulfate at water/hexane interface

Kinsi Motomura, Makoto Aratono, Norihiro Matubayasi, Ryohei Matuura

研究成果: ジャーナルへの寄稿記事

53 引用 (Scopus)

抄録

The thermodynamic treatment of adsorption developed in Part I has been extended so as to include the case of strong electrolytes. By applying the thermodynamic relations to experimental results obtained for the system consisting of aqueous solution of sodium dodecyl sulfate (SDS) and hexane, the thermodynamic quantities of interface formation and partial molar quantities of the adsorption have been evaluated. Their values have been compared with the corresponding ones of tetradecanol described in Part II. It has been observed that SDS has a negative entropy of interface formation which is smaller than tetradecanol, while it has a larger interfacial concentration. This value is closely related to a larger positive value of the volume of interface formation. The above view has been confirmed by changes in the mean partial molar entropy and volume at adsorption. It has also been found from the energy of interface formation and partial molar energy of the adsorption that the adsorption of SDS from aqueous solution is inferior energetically to that of tetradecanol from hexane solution.

元の言語英語
ページ(範囲)247-254
ページ数8
ジャーナルJournal of Colloid and Interface Science
67
発行部数2
DOI
出版物ステータス出版済み - 1 1 1978

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Sodium dodecyl sulfate
Hexanes
Hexane
sodium sulfates
Sodium Dodecyl Sulfate
Thermodynamics
Adsorption
thermodynamics
adsorption
Water
water
Entropy
entropy
aqueous solutions
Electrolytes
electrolytes
energy

All Science Journal Classification (ASJC) codes

  • Colloid and Surface Chemistry
  • Physical and Theoretical Chemistry
  • Surfaces and Interfaces

これを引用

Thermodynamic studies on adsorption at interfaces. III. Sodium dodecyl sulfate at water/hexane interface. / Motomura, Kinsi; Aratono, Makoto; Matubayasi, Norihiro; Matuura, Ryohei.

:: Journal of Colloid and Interface Science, 巻 67, 番号 2, 01.01.1978, p. 247-254.

研究成果: ジャーナルへの寄稿記事

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N2 - The thermodynamic treatment of adsorption developed in Part I has been extended so as to include the case of strong electrolytes. By applying the thermodynamic relations to experimental results obtained for the system consisting of aqueous solution of sodium dodecyl sulfate (SDS) and hexane, the thermodynamic quantities of interface formation and partial molar quantities of the adsorption have been evaluated. Their values have been compared with the corresponding ones of tetradecanol described in Part II. It has been observed that SDS has a negative entropy of interface formation which is smaller than tetradecanol, while it has a larger interfacial concentration. This value is closely related to a larger positive value of the volume of interface formation. The above view has been confirmed by changes in the mean partial molar entropy and volume at adsorption. It has also been found from the energy of interface formation and partial molar energy of the adsorption that the adsorption of SDS from aqueous solution is inferior energetically to that of tetradecanol from hexane solution.

AB - The thermodynamic treatment of adsorption developed in Part I has been extended so as to include the case of strong electrolytes. By applying the thermodynamic relations to experimental results obtained for the system consisting of aqueous solution of sodium dodecyl sulfate (SDS) and hexane, the thermodynamic quantities of interface formation and partial molar quantities of the adsorption have been evaluated. Their values have been compared with the corresponding ones of tetradecanol described in Part II. It has been observed that SDS has a negative entropy of interface formation which is smaller than tetradecanol, while it has a larger interfacial concentration. This value is closely related to a larger positive value of the volume of interface formation. The above view has been confirmed by changes in the mean partial molar entropy and volume at adsorption. It has also been found from the energy of interface formation and partial molar energy of the adsorption that the adsorption of SDS from aqueous solution is inferior energetically to that of tetradecanol from hexane solution.

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