Thermodynamics of multicomponent monolayers. IV. Monolayer penetration

Kinsi Motomura, Yoshiteru Hayami, Makoto Aratono, Ryohei Matuura

研究成果: ジャーナルへの寄稿学術誌査読

32 被引用数 (Scopus)


With the view that an insoluble monolayer is regarded as a limiting state of the adsorbed film at the air/water interface, the thermodynamic treatment of penetrated monolayer has been developed by extending the rigorous thermodynamics of mixed monolayer presented in Part I of this series and that of the adsorbed film at the air/water interface. The equations of the thermodynamic quantities of penetration have been derived on the basis of the surface excess quantities defined by Hansen; their evaluation has been found to require the measurement of surface tension as a function of the composition of the penetrating substance and the temperature over the whole range of area per mole of film-forming substance. It has been claimed that there is considerable doubt as to the validity of Pethica's equation.

ジャーナルJournal of Colloid And Interface Science
出版ステータス出版済み - 1月 1 1982

!!!All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 生体材料
  • 表面、皮膜および薄膜
  • コロイド化学および表面化学


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