Thermoelectric properties of double-perovskite oxide Sr2-xM xFeMoO6 [M = Ba, La)

Tohra Sugahara, Michitaka Ohtaki, Takeshi Souma

    研究成果: ジャーナルへの寄稿記事

    25 引用 (Scopus)

    抄録

    Doping effects for the A-site in double-perovskite type oxide Sr 2-xMxFeMoO6 (M = Ba, La) are investigated on the thermoelectric properties of the oxides. The Seebeck coefficient, S, shows that all the samples of both Ba- and La-doped Sr2FeMoO6 systems are n-type over the measured temperature range. In particular, the power factor, S2 σ, of the Sr2FeMoO6 system largely increased with increasing Ba doping level up to x = 0.3. As a consequence, S2 σ of Sr1.7 Bao 0.3FeMoO6 reached ca. 0.8 × 10-4 W/mK2, the largest value of all the samples in this study. The thermal conductivity, κ, shows a general trend in which the value decreases from ca. 1 W/mK at room temperature to ca. 0.7 W/mK at 1100 K. The dimensionless figure of merit, ZT, of the Badoped samples increased with increasing Ba doping level. Moreover, the ZT value drastically increased above 700 K due to the S2 σ value increasing above 700 K and the κ value decreasing monotonically. As a result, the ZT value of Sr 1.7Ba0.3FeMoO6 reached 0.31 at 1100 K.

    元の言語英語
    ページ(範囲)1278-1282
    ページ数5
    ジャーナルJournal of the Ceramic Society of Japan
    116
    発行部数1360
    DOI
    出版物ステータス出版済み - 1 1 2008

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    Perovskite
    Oxides
    Doping (additives)
    oxides
    Seebeck coefficient
    Seebeck effect
    figure of merit
    Thermal conductivity
    thermal conductivity
    trends
    Temperature
    room temperature
    perovskite
    temperature

    All Science Journal Classification (ASJC) codes

    • Ceramics and Composites
    • Chemistry(all)
    • Condensed Matter Physics
    • Materials Chemistry

    これを引用

    Thermoelectric properties of double-perovskite oxide Sr2-xM xFeMoO6 [M = Ba, La). / Sugahara, Tohra; Ohtaki, Michitaka; Souma, Takeshi.

    :: Journal of the Ceramic Society of Japan, 巻 116, 番号 1360, 01.01.2008, p. 1278-1282.

    研究成果: ジャーナルへの寄稿記事

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    abstract = "Doping effects for the A-site in double-perovskite type oxide Sr 2-xMxFeMoO6 (M = Ba, La) are investigated on the thermoelectric properties of the oxides. The Seebeck coefficient, S, shows that all the samples of both Ba- and La-doped Sr2FeMoO6 systems are n-type over the measured temperature range. In particular, the power factor, S2 σ, of the Sr2FeMoO6 system largely increased with increasing Ba doping level up to x = 0.3. As a consequence, S2 σ of Sr1.7 Bao 0.3FeMoO6 reached ca. 0.8 × 10-4 W/mK2, the largest value of all the samples in this study. The thermal conductivity, κ, shows a general trend in which the value decreases from ca. 1 W/mK at room temperature to ca. 0.7 W/mK at 1100 K. The dimensionless figure of merit, ZT, of the Badoped samples increased with increasing Ba doping level. Moreover, the ZT value drastically increased above 700 K due to the S2 σ value increasing above 700 K and the κ value decreasing monotonically. As a result, the ZT value of Sr 1.7Ba0.3FeMoO6 reached 0.31 at 1100 K.",
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    AB - Doping effects for the A-site in double-perovskite type oxide Sr 2-xMxFeMoO6 (M = Ba, La) are investigated on the thermoelectric properties of the oxides. The Seebeck coefficient, S, shows that all the samples of both Ba- and La-doped Sr2FeMoO6 systems are n-type over the measured temperature range. In particular, the power factor, S2 σ, of the Sr2FeMoO6 system largely increased with increasing Ba doping level up to x = 0.3. As a consequence, S2 σ of Sr1.7 Bao 0.3FeMoO6 reached ca. 0.8 × 10-4 W/mK2, the largest value of all the samples in this study. The thermal conductivity, κ, shows a general trend in which the value decreases from ca. 1 W/mK at room temperature to ca. 0.7 W/mK at 1100 K. The dimensionless figure of merit, ZT, of the Badoped samples increased with increasing Ba doping level. Moreover, the ZT value drastically increased above 700 K due to the S2 σ value increasing above 700 K and the κ value decreasing monotonically. As a result, the ZT value of Sr 1.7Ba0.3FeMoO6 reached 0.31 at 1100 K.

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