Three-way-output response system by electric potential: UV-vis, CD, and fluorescence spectral changes upon electrolysis of the chiral ester of tetracyanoanthraquinodimethane

Hiroki Higuchi, Koji Ichioka, Hidetoshi Kawai, Kenshu Fujiwara, Masakazu Ohkita, Takashi Tsuji, Takanori Suzuki

研究成果: Contribution to journalArticle査読

22 被引用数 (Scopus)

抄録

The newly prepared tetracyanoanthraquinodimethane (TCNAQ) derivatives 1a,b with a chiral auxiliary are good electron acceptors and exhibit weak circular dichroism (CD) based on the absorption of TCNAQ. The twin-type electron acceptor 1c with two TCNAQ units shows larger ellipticity by exciton coupling. UV-vis, CD, and fluorescence spectra were changed drastically upon electrochemical reduction of 1c, which demonstrates the unprecedented three-way-output response system.

本文言語英語
ページ(範囲)3027-3030
ページ数4
ジャーナルTetrahedron Letters
45
15
DOI
出版ステータス出版済み - 4 5 2004

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

フィンガープリント 「Three-way-output response system by electric potential: UV-vis, CD, and fluorescence spectral changes upon electrolysis of the chiral ester of tetracyanoanthraquinodimethane」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル