Titania-added Ce 0.6 la 0.4 O 2-δ for the buffer layer of high-performance solid oxide fuel cells using doped lanthanum gallate electrolyte film

Jong Eun Hong, Toru Inagaki, Shintaro Ida, Tatsumi Ishihara

研究成果: Contribution to journalArticle

9 引用 (Scopus)

抜粋

Decrease in sintering temperature of lanthanum-doped ceria (Ce 0.6La 0.4O 2-δ, LDC), which was used as a buffer layer, was investigated using sintering additives such as Ag 2O, ZnO, BaO, CaO, Bi 2O 3, RuO 2, and TiO 2 for preventing NiO diffusion into Sr- and Mg-doped LaGaO 3 (LSGM) electrolyte film prepared by screen printing and co-firing method. It was found that TiO 2 was the most effective in decreasing the sintering temperature to 1473 K, which was 300 K lower than that of LDC, and increasing the electrical conductivity. Ti addition in LDC was attributed to increased mass transportation caused by compensation for lattice mismatch and defect dissociation resulted in improved sintering density and electrical conductivity. However, Ti-LDC buffer layer could not completely prevent NiO diffusion into the LSGM electrolyte, although it was effective in reducing the diffusion content-probably because of the low sintering temperature of Ti-LDC. The use of fast sintering (a heating/cooling rate of 600 K/h and a holding time of 3 h) further decreased NiO diffusion into the electrolyte. Accordingly, theoretical open-circuit voltage and improved power density were attributed to reduced electron hole conduction and ohmic resistance that were assigned to suppressed NiO diffusion into the LSGM electrolyte.

元の言語英語
ページ(範囲)3588-3596
ページ数9
ジャーナルJournal of the American Ceramic Society
95
発行部数11
DOI
出版物ステータス出版済み - 11 1 2012

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

フィンガープリント Titania-added Ce <sub>0.6</sub> la <sub>0.4</sub> O <sub>2-δ</sub> for the buffer layer of high-performance solid oxide fuel cells using doped lanthanum gallate electrolyte film' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用