Toward advanced functional systems: Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes

Leire Ruiz-Rubio, Beñat Artetxe, Leyre Pérez-Álvarez, Jagoba Martín-Caballero, Tatsumi Ishihara, Juan M. Gutiérrez-Zorrilla, José Luis Vilas-Vilela

研究成果: Contribution to journalArticle

抜粋

In this work the immobilization of hybrid polyoxometalates (POMs) onto functional polymeric surfaces is exposed and discussed. Thus, various hybrid polymer-inorganic films were prepared by anchoring selected hybrid POMs onto tailored polymeric surfaces that consisted of breath figures (BFs) made of polystyrene-b-poly(acrylic acid)/polystyrene (PS-b-PAA/PS) blends. Functionalization of the BF films was performed by selective arrangement of acrylic acid groups of the amphiphilic block copolymer on the surface pores because of their affinition for the water condensed during breath figure formation. These carboxylic acid functional groups contained within the PAA blocks were then employed to anchor [Cu(cyclam)][{Cu(cyclam)}2(V10O28)]·10H2O (1-CuV10) and [{Cu(cyclam)}(VO3)2]·5H2O (1-CuV1), hybrid POMs by immersing the films into aqueous solutions of the in situ formed hybrid clusters, resulting in the hybrid films BF1 and BF2, respectively. Superficial analysis of these hybrid polymeric films was carried out by the sophisticated ion beam-based technique time-of-flight secondary ion mass spectrometry (ToF-SIMS) that was revealed to be an excellent method for the superficial compositional mapping of patterned surfaces.

元の言語英語
記事番号2313
ジャーナルMolecules
24
発行部数12
DOI
出版物ステータス出版済み - 2019

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Chemistry (miscellaneous)
  • Molecular Medicine
  • Pharmaceutical Science
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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    Ruiz-Rubio, L., Artetxe, B., Pérez-Álvarez, L., Martín-Caballero, J., Ishihara, T., Gutiérrez-Zorrilla, J. M., & Vilas-Vilela, J. L. (2019). Toward advanced functional systems: Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes. Molecules, 24(12), [2313]. https://doi.org/10.3390/molecules24122313