Toward higher nuclearity: Tetranuclear cobalt(II) metallogrid exhibiting spin crossover

Shu Qi Wu; Yi Tong Wang; Ai Li Cui; Hui Zhong Kou

doi:10.1021/ic402971a

Toward higher nuclearity: Tetranuclear cobalt(II) metallogrid exhibiting spin crossover

Shu Qi Wu, Yi Tong Wang, Ai Li Cui, Hui Zhong Kou

研究成果: Contribution to journal › Article › 査読

27 被引用数 (Scopus)

抄録

Supramolecular strategy was employed to achieve the highest nuclearity Co(II) cluster exhibiting spin-crossover (SCO) behavior. Magnetic susceptibility characterization of the Co₄^II complex shows that two different spin-transition processes occur. The SCO behavior is directed by the partially deprotonated polydentate ligand, which favors the structural distortion required by the spin transition.

本文言語	英語
ページ（範囲）	2613-2618
ページ数	6
ジャーナル	Inorganic chemistry
巻	53
号	5
DOI	https://doi.org/10.1021/ic402971a
出版ステータス	出版済み - 3 3 2014
外部発表	はい

All Science Journal Classification (ASJC) codes

物理化学および理論化学
無機化学

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10.1021/ic402971a

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title = "Toward higher nuclearity: Tetranuclear cobalt(II) metallogrid exhibiting spin crossover",

abstract = "Supramolecular strategy was employed to achieve the highest nuclearity Co(II) cluster exhibiting spin-crossover (SCO) behavior. Magnetic susceptibility characterization of the Co4II complex shows that two different spin-transition processes occur. The SCO behavior is directed by the partially deprotonated polydentate ligand, which favors the structural distortion required by the spin transition.",

author = "Wu, {Shu Qi} and Wang, {Yi Tong} and Cui, {Ai Li} and Kou, {Hui Zhong}",

year = "2014",

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AU - Wu, Shu Qi

AU - Wang, Yi Tong

AU - Cui, Ai Li

AU - Kou, Hui Zhong

PY - 2014/3/3

Y1 - 2014/3/3

N2 - Supramolecular strategy was employed to achieve the highest nuclearity Co(II) cluster exhibiting spin-crossover (SCO) behavior. Magnetic susceptibility characterization of the Co4II complex shows that two different spin-transition processes occur. The SCO behavior is directed by the partially deprotonated polydentate ligand, which favors the structural distortion required by the spin transition.

AB - Supramolecular strategy was employed to achieve the highest nuclearity Co(II) cluster exhibiting spin-crossover (SCO) behavior. Magnetic susceptibility characterization of the Co4II complex shows that two different spin-transition processes occur. The SCO behavior is directed by the partially deprotonated polydentate ligand, which favors the structural distortion required by the spin transition.

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Toward higher nuclearity: Tetranuclear cobalt(II) metallogrid exhibiting spin crossover

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