Towards an accurate estimation of the isosteric heat of adsorption – A correlation with the potential theory

Ahmed A. Askalany, Bidyut Baran Saha

研究成果: Contribution to journalArticle

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Accurate estimation of the isosteric heat of adsorption is mandatory for a good modeling of adsorption processes. In this paper a thermodynamic formalism on adsorbed phase volume which is a function of adsorption pressure and temperature has been proposed for the precise estimation of the isosteric heat of adsorption. The estimated isosteric heat of adsorption using the new correlation has been compared with measured values of prudently selected several adsorbent-refrigerant pairs from open literature. Results showed that the proposed isosteric heat of adsorption correlation fits the experimentally measured values better than the Clausius-Clapeyron equation.

元の言語英語
ページ(範囲)59-63
ページ数5
ジャーナルJournal of Colloid And Interface Science
490
DOI
出版物ステータス出版済み - 3 15 2017

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Surfaces, Coatings and Films
  • Colloid and Surface Chemistry

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