Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

Ryoichi Kuwano, Yutaka Kondo, Tsuyoshi Shirahama

研究成果: ジャーナルへの寄稿記事

53 引用 (Scopus)

抄録

(Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.

元の言語英語
ページ(範囲)2973-2975
ページ数3
ジャーナルOrganic Letters
7
発行部数14
DOI
出版物ステータス出版済み - 7 7 2005

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Sulfones
sulfones
Carbonates
Palladium
Dimethyl Sulfoxide
Ether
palladium
ethers
carbonates
Substitution reactions
Sodium
sodium
substitutes
sodium carbonate

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution. / Kuwano, Ryoichi; Kondo, Yutaka; Shirahama, Tsuyoshi.

:: Organic Letters, 巻 7, 番号 14, 07.07.2005, p. 2973-2975.

研究成果: ジャーナルへの寄稿記事

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