Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

Ryoichi Kuwano; Yutaka Kondo; Tsuyoshi Shirahama

doi:10.1021/ol0509787

Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

Ryoichi Kuwano, Yutaka Kondo, Tsuyoshi Shirahama

複合領域化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

60 被引用数 (Scopus)

抄録

(Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η³-C₃H₅)Cl] ₂ and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.

本文言語	英語
ページ（範囲）	2973-2975
ページ数	3
ジャーナル	Organic Letters
巻	7
号	14
DOI	https://doi.org/10.1021/ol0509787
出版ステータス	出版済み - 7月 7 2005

!!!All Science Journal Classification (ASJC) codes

生化学
物理化学および理論化学
有機化学

文献へのアクセス

10.1021/ol0509787

他のファイルとリンク

引用スタイル

@article{c0d181d708074c79b03a79a073c837dc,

title = "Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution",

abstract = "(Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.",

author = "Ryoichi Kuwano and Yutaka Kondo and Tsuyoshi Shirahama",

year = "2005",

month = jul,

day = "7",

doi = "10.1021/ol0509787",

language = "English",

volume = "7",

pages = "2973--2975",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "14",

}

TY - JOUR

T1 - Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

AU - Kuwano, Ryoichi

AU - Kondo, Yutaka

AU - Shirahama, Tsuyoshi

PY - 2005/7/7

Y1 - 2005/7/7

N2 - (Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.

AB - (Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.

UR - http://www.scopus.com/inward/record.url?scp=22244478987&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=22244478987&partnerID=8YFLogxK

U2 - 10.1021/ol0509787

DO - 10.1021/ol0509787

M3 - Article

C2 - 15987183

AN - SCOPUS:22244478987

VL - 7

SP - 2973

EP - 2975

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 14

ER -

Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

抄録

!!!All Science Journal Classification (ASJC) codes

文献へのアクセス

他のファイルとリンク

フィンガープリント

引用スタイル