Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

Ryoichi Kuwano; Yutaka Kondo; Tsuyoshi Shirahama

doi:10.1021/ol0509787

Transformation of carbonates into sulfones at the benzylic position via palladium-catalyzed benzylic substitution

Ryoichi Kuwano, Yutaka Kondo, Tsuyoshi Shirahama

複合領域化学

研究成果: Contribution to journal › Article › 査読

56 被引用数 (Scopus)

抄録

(Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η³-C₃H₅)Cl] ₂ and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.

本文言語	英語
ページ（範囲）	2973-2975
ページ数	3
ジャーナル	Organic Letters
巻	7
号	14
DOI	https://doi.org/10.1021/ol0509787
出版ステータス	出版済み - 7 7 2005

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

文献へのアクセス

10.1021/ol0509787

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引用スタイル

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abstract = "(Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.",

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AB - (Chemical Equation Presented) The nucleophilic substitution of benzylic carbonates with sodium arenesulfinates was catalyzed by the palladium complex generated in situ from [Pd(η3-C3H5)Cl] 2 and DPEphos [bis(2-diphenylphosphinophenyl)ether]. The catalytic reaction proceeded in DMSO at 80°C and gave a variety of benzylic sulfones in high yields.

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