Transient Protection of Organic Azides from Click Reactions with Alkynes by Phosphazide Formation

Tomohiro Meguro, Suguru Yoshida, Kazunobu Igawa, Katsuhiko Tomooka, Takamitsu Hosoya

研究成果: Contribution to journalArticle査読

21 被引用数 (Scopus)

抄録

A method for protecting organic azides from click reactions with alkynes is reported. Treatment of azides with Amphos affords phosphazides, which are stable under click reaction conditions and are easily converted back to azides by treatment with elemental sulfur. Thus, the method allows for facile modification of azide compounds via site-selective click reactions.

本文言語英語
ページ(範囲)4126-4130
ページ数5
ジャーナルOrganic letters
20
13
DOI
出版ステータス出版済み - 7 6 2018

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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