TY - JOUR
T1 - Transition metal-catalyzed highly efficient and novel transformations -Development of reactions using group 7 and other transition metal catalysts
AU - Kuninobu, Yoichiro
PY - 2013/7/24
Y1 - 2013/7/24
N2 - Rhenium and manganese-catalyzed regioselective insertion of unsaturated molecules into aromatic and olefinic C-H bonds have been achieved. In some cases, successive intramolecular nucleophilic cyclization proceeded. We have also succeeded in regioselective insertion of alkynes into a non-strained C-C single bond of 1,3-dicarbonyl compounds using a rhenium or manganese catalyst. In addition, we have succeeded in regio-and stereo-defined cycloaddition reactions. By using a rhodium or palladium catalyst, we have achieved direct and efficient carbon-heteroatom bond formations via C-H bond activation.
AB - Rhenium and manganese-catalyzed regioselective insertion of unsaturated molecules into aromatic and olefinic C-H bonds have been achieved. In some cases, successive intramolecular nucleophilic cyclization proceeded. We have also succeeded in regioselective insertion of alkynes into a non-strained C-C single bond of 1,3-dicarbonyl compounds using a rhenium or manganese catalyst. In addition, we have succeeded in regio-and stereo-defined cycloaddition reactions. By using a rhodium or palladium catalyst, we have achieved direct and efficient carbon-heteroatom bond formations via C-H bond activation.
UR - http://www.scopus.com/inward/record.url?scp=84880364070&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84880364070&partnerID=8YFLogxK
U2 - 10.5059/yukigoseikyokaishi.71.425
DO - 10.5059/yukigoseikyokaishi.71.425
M3 - Review article
AN - SCOPUS:84880364070
VL - 71
SP - 425
EP - 432
JO - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
JF - Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
SN - 0037-9980
IS - 5
ER -