@article{a019573ced764773ad1e786a60a3a506,
title = "Transition-Metal-Free β-Selective C-Glycosylation of β-Glycosyl Boronates via Stereoretentive 1,2-Migration",
abstract = "C-Glycoside analogues of native glycans are useful molecular tools for medicinal chemistry and chemical biology due to their resistance to cellular glycoside hydrolases. We previously reported an α-selective direct C-glycosylation of 2-deoxy-β-glycosyl boronate through a Ni/photoredox-catalyzed stereoinvertive cross-coupling reaction. Here we report a complementary stereoretentive synthetic method for the preparation of β-C-glycosides from a similar boronate precursor through the addition of a C(sp2) anion followed by 1,2-migration of the glycosyl donor.",
author = "Hiroki Yasutomi and Daiki Takeda and Makoto Yoritate and Shuhei Higashibayashi and Takeshi Sugai and Go Hirai",
note = "Funding Information: This study was partially supported by PRIME, BINDS, and SCARDA from the Japan Agency for Medical Research and Development (AMED), JSPS KAKENHI (grants nos. 22K14683, 21K19053, and 21H02070), the Mizutani Foundation for Glycoscience, and the Sumitomo Foundation. Publisher Copyright: {\textcopyright} 2022. Thieme. All rights reserved.",
year = "2023",
month = mar,
day = "1",
doi = "10.1055/a-1989-2541",
language = "English",
volume = "34",
pages = "347--352",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "4",
}