Translational and rotational energy measurements of desorbed water molecules in their vibrational ground state following 157 nm irradiation of amorphous solid water

Tetsuya Hama, Masaaki Yokoyama, Akihiro Yabushita, Masahiro Kawasaki, Naoki Watanabe

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

Water ice is the major solid component in a variety of astrophysical environments, e.g., cold and dense molecular clouds. Photodesorption plays a dominant role in consuming ice in such cold regions. In this study, photodesorption of vibrationally ground-state H2O(v = 0) from amorphous solid water has been investigated at 157 nm. Using a resonance-enhanced multiphoton ionization technique, the translational and rotational energy distributions of photodesorbed H2O(v = 0) were measured, i.e., Boltzmann distributions at 1800 and 300 K, respectively. These energies are in good accordance with those predicted by classical molecular calculations for water photodesorption due to a kick-out mechanism following absorption of a single photon; hot H atom released by photodissociation of H2O in ice transfers enough momentum to another H2O molecule to kick it off the surface. Desorption of D2O(v = 0) following 193 nm photoirradiation of a D2O/H2S mixed ice was investigated to provide further direct evidence for the operation of a kick-out mechanism. The other desorption mechanisms were also discussed in the context of possible photodesorption of vibrationally excited H2O.

本文言語英語
ページ(範囲)1011-1015
ページ数5
ジャーナルNuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms
269
9
DOI
出版ステータス出版済み - 5 1 2011
外部発表はい

All Science Journal Classification (ASJC) codes

  • 核物理学および高エネルギー物理学
  • 器械工学

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