Transport properties of comb-type grafted and normal-type N-isopropylacrylamide hydrogel

Masahiko Annaka, Masaaki Sugiyama, Masaki Kasai, Takayuki Nakahira, Toyoaki Matsuura, Hiroko Seki, Takao Aoyagi, Teruo Okano

研究成果: ジャーナルへの寄稿記事

22 引用 (Scopus)

抜粋

Transport properties of the comb-type grafted and normal-type N-isopropylacrylamide (NIPA) gel are investigated by gel filtration chromatography and a pulsed field gradient NMR technique with known standard probe molecules in terms of molecular weight cutoff and diffusion coefficient in and through the gels, respectively. The incorporation of NIPA grafted chains into NIPA gel makes the effective mesh size smaller and induces the additional friction between the probe molecule and gel network. One may control the maximum mesh size of the NIPA gel and thus the effective diffusivity of a probe molecule within a gel by incorporating grafted chains and by adjusting the temperature.

元の言語英語
ページ(範囲)7377-7383
ページ数7
ジャーナルLangmuir
18
発行部数20
DOI
出版物ステータス出版済み - 10 1 2002
外部発表Yes

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

これを引用

Annaka, M., Sugiyama, M., Kasai, M., Nakahira, T., Matsuura, T., Seki, H., ... Okano, T. (2002). Transport properties of comb-type grafted and normal-type N-isopropylacrylamide hydrogel. Langmuir, 18(20), 7377-7383. https://doi.org/10.1021/la025876t