Triplet–triplet upconversion enhanced by spin–orbit coupling in organic light-emitting diodes

研究成果: ジャーナルへの寄稿記事

4 引用 (Scopus)

抜粋

Triplet–triplet upconversion, in which two triplet excitons are converted to one singlet exciton, is a well-known approach to exceed the limit of electroluminescence quantum efficiency in conventional fluorescence-based organic light-emitting diodes. Considering the spin multiplicity of triplet pairs, upconversion efficiency is usually limited to 20%. Although this limit can be exceeded when the energy of a triplet pair is lower than that of a second triplet excited state, such as for rubrene, it is generally difficult to engineer the energy levels of higher triplet excited states. Here, we investigate the upconversion efficiency of a series of new anthracene derivatives with different substituents. Some of these derivatives show upconversion efficiencies close to 50% even though the calculated energy levels of the second triplet excited states are lower than twice the lowest triplet energy. A possible upconversion mechanism is proposed based on the molecular structures and quantum chemical calculations.

元の言語英語
記事番号5283
ジャーナルNature communications
10
発行部数1
DOI
出版物ステータス出版済み - 12 1 2019

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

フィンガープリント Triplet–triplet upconversion enhanced by spin–orbit coupling in organic light-emitting diodes' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用