Triply N-confused hexaphyrins: Near-infrared luminescent dyes with a triangular shape

Yong Shu Xie; Keisuke Yamaguchi; Motoki Toganoh; Hidemitsu Uno; Masaaki Suzuki; Shigeki Mori; Shohei Saito; Atsuhiro Osuka; Hiroyuki Furuta

doi:10.1002/anie.200900596

Triply N-confused hexaphyrins: Near-infrared luminescent dyes with a triangular shape

Yong Shu Xie, Keisuke Yamaguchi, Motoki Toganoh, Hidemitsu Uno, Masaaki Suzuki, Shigeki Mori, Shohei Saito, Atsuhiro Osuka, Hiroyuki Furuta

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

68 被引用数 (Scopus)

抄録

Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.

本文言語	英語
ページ（範囲）	5496-5499
ページ数	4
ジャーナル	Angewandte Chemie - International Edition
巻	48
号	30
DOI	https://doi.org/10.1002/anie.200900596
出版ステータス	出版済み - 7月 13 2009

!!!All Science Journal Classification (ASJC) codes

触媒
化学 (全般)

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10.1002/anie.200900596

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AU - Xie, Yong Shu

AU - Yamaguchi, Keisuke

AU - Toganoh, Motoki

AU - Uno, Hidemitsu

AU - Suzuki, Masaaki

AU - Mori, Shigeki

AU - Saito, Shohei

AU - Osuka, Atsuhiro

AU - Furuta, Hiroyuki

PY - 2009/7/13

Y1 - 2009/7/13

N2 - Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.

AB - Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.

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Triply N-confused hexaphyrins: Near-infrared luminescent dyes with a triangular shape

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!!!All Science Journal Classification (ASJC) codes

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