Two-dimensional triangular-lattice Cu(OH)Cl, belloite, as a magnetodielectric system

Xu Guang Zheng, Ichihiro Yamauchi, Shigeto Kitajima, Masayoshi Fujihala, M. Maki, Sanghyun Lee, Masato Hagihala, S. Torii, T. Kamiyama, Tatsuya Kawae

研究成果: Contribution to journalArticle査読

5 被引用数 (Scopus)

抄録

Quantum spins on a triangular lattice may bring out intriguing and exotic quantum ground states. Here we report a magnetodielectric system of CuOHCl wherein S=1/2Cu2+ spins constitute a two-dimensional triangular lattice with the layers weakly coupled via Cl-H-O bonding. Despite strong magnetic interactions, as expected from the relatively high value of θCW=-100K, antiferromagnetic transition occurred at TN=11K, followed by an uprising turn of the magnetic susceptibility below ∼7 K. Neutron-diffraction experiment revealed a coplanar spin structure on the triangular lattice below the TN, with each spin pointing toward the center of a triangle. Of the three spins on a triangle, two are antiparallel and the third one is angled 120 to the antiparallel spins. A concerted effect of geometric frustration in the triangular lattice and superexchange interactions through a zig-zag path via double Cu-O-Cu and double Cu-Cl-Cu bridges counted for this spin arrangement. Further investigation using dielectric constant and heat capacity measurements, as well as a microscopic probe of muon spin rotation, revealed a magnetodielectric effect and the possibility of multiferroic transition at T∗∼5K, which is suspected to be in close relation to geometric frustration in this triangular lattice. The present paper presents a magnetodielectric system on a two-dimensional triangular lattice with chemical stoichiometry. It can also serve as a rare reference to the hotly debated quantum spin-orbital liquid compound LiNiO2.

本文言語英語
論文番号104401
ジャーナルPhysical Review Materials
2
10
DOI
出版ステータス出版済み - 10 2 2018

All Science Journal Classification (ASJC) codes

  • 材料科学(全般)
  • 物理学および天文学(その他)

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