Usage and development of optically active cyclic 1,2-diols

Hiroshi Suemune, Mariko Aso

研究成果: ジャーナルへの寄稿記事

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Optically active diols are one of the useful groups of compounds for asymmetric reaction as a chiral auxiliary or ligand. Among them, cyclic 1,2-diols are characteristic of the restricted conformation. In this review, we wish to report the use of these compounds for the development of asymmetric reactions such as ring transformations based on intramolecular and intermolecular aldol reactions, and carba-spirocyclization, in which cyclic 1,2-diols are added as a chiral source in combination with a Lewis acid. In addition, the synthesis of optically active cyclic diene comp pounds starting from cyclic 1,2-diols is also discussed.

元の言語英語
ページ(範囲)807-814
ページ数8
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
63
発行部数8
DOI
出版物ステータス出版済み - 8 2005

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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