Usage of the carboxylate leaving group in transition-metal-catalyzed cross-coupling and related reactions

研究成果: Contribution to journalArticle査読

8 被引用数 (Scopus)

抄録

This account describes our recent work on catalytic cross-coupling reactions using carboxylate and carbonate leaving groups in the electrophilic substrate. Some bisphosphine-chelated palladium(O) complexes are effective for the cleavage of benzylic C-O bonds in benzyl carbonates and acetates. This C-O bond cleavage was utilized in catalytic reactions of these benzylic esters; the nucleophilic benzylic substitutions and the crosscoupling reactions with organometallic compounds. Furthermore, vinyl acetate was proved to work as the coupling partner of arylboronates in the presence of [RhCl(cod)] 2-DPPB. Interestingly, the organoborons react selectively at the position β to the leaving group in the alkenyl ester when the rhodium-catalyzed reaction is conducted in the absence of the bisphosphine.

本文言語英語
ページ(範囲)1263-1270
ページ数8
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
69
11
DOI
出版ステータス出版済み - 11 2011

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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