Vapor-liquid distribution of oil in coal liquefaction process

Koichi Ikeda, Seiichi Okada, Michiharu Mochizuki, Tetsuya Takeda, Kouji Sakawaki, Kenji Inokuchi, Jun Ichiro Hayashi, Tadatoshi Chiba

研究成果: Contribution to journalArticle査読

抄録

Measurements and analyses were performed on high-temperature and high-pressure vapor-liquid distribution in the hot separator and the reactor of a 1-t/d coal liquefaction process supporting unit (PSU), which simulated the NEDOL process. The vapor-to-liquid molar ratio, measured for the individual fractions of coal-derived oil in the hot separator, was found to decrease from 1.0 to 0.01 with an increase in the average boiling-point temperature from 373 to 798 K. The measured ratios generally coincided well with those calculated using the Soave-Redlich-Kwong (SRK) equation, with a slight discrepancy for fractions having boiling point temperatures lower than ca. 470 K. The slurry, when directly collected from the reactor, was significantly concentrated due to vaporization of oil. Based on the degree of concentration of the slurry, the fractional weight of vaporized oil was estimated to 0.7 or greater, depending on the reactor temperature and the feed ratio of gas to slurry. The observed fractional weights were also well approximated based on the SRK equation. These findings were utilized in operation and optimization of a 150-t/d pilot plant for the NEDOL process.

本文言語英語
ページ(範囲)100-106
ページ数7
ジャーナルkagaku kogaku ronbunshu
29
1
DOI
出版ステータス出版済み - 1 2003
外部発表はい

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)

フィンガープリント

「Vapor-liquid distribution of oil in coal liquefaction process」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル