Versatile Molecular Functionalization for Inhibiting Concentration Quenching of Thermally Activated Delayed Fluorescence

Jiyoung Lee, Naoya Aizawa, Masaki Numata, Chihaya Adachi, Takuma Yasuda

研究成果: Contribution to journalArticle

104 引用 (Scopus)

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Researchers emonstrate that even a small modulation in molecular geometric structures greatly affects concentration quenching of thermally activated delayed fluorescence (TADF) and can enhance the quantum efficiencies of solid-state photoluminescence (PL) and electroluminescence (EL). The exciton-quenching rates of TADF emitters show an exponential dependence on their intermolecular distance in thin films, revealing that electron-exchange interactions of triplet excitons, as described by the Dexter energy-transfer model, dominate the concentration quenching of TADF. This mechanism stands in marked contrast to those of conventional fluorescent and phosphorescent emitters involving Förster energy transfer.

元の言語英語
記事番号1604856
ジャーナルAdvanced Materials
29
発行部数4
DOI
出版物ステータス出版済み - 1 1 2017

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

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