抄録
The Mo-based polyoxometalates containing mono- and dicobalt(iii) catalyst cores, [CoMo 6O 24H 6] 3- and [Co 2Mo 10O 38H 4] 6-, were found to serve as O 2-evolving catalysts in a system consisting of tris(2,2′-bipyridine)ruthenium(ii) (Ru(bpy) 3 2+) and sodium persulfate (S 2O2-8) in an aqueous borate buffer solution at pH 8.0. Kinetics of O 2 evolution reveals that the higher cobalt nuclearity is not necessary to attain the highly active nature of the catalyst.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 1653-1655 |
| ページ数 | 3 |
| ジャーナル | Chemical Communications |
| 巻 | 48 |
| 発行部数 | 11 |
| DOI | |
| 出版物ステータス | 出版済み - 2 4 2012 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
これを引用
Visible light-induced water oxidation catalyzed by molybdenum-based polyoxometalates with mono- and dicobalt(iii) cores as oxygen-evolving centers. / Tanaka, Saya; Annaka, Masahiko; Sakai, Ken.
：: Chemical Communications, 巻 48, 番号 11, 04.02.2012, p. 1653-1655.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - Visible light-induced water oxidation catalyzed by molybdenum-based polyoxometalates with mono- and dicobalt(iii) cores as oxygen-evolving centers
AU - Tanaka, Saya
AU - Annaka, Masahiko
AU - Sakai, Ken
PY - 2012/2/4
Y1 - 2012/2/4
N2 - The Mo-based polyoxometalates containing mono- and dicobalt(iii) catalyst cores, [CoMo 6O 24H 6] 3- and [Co 2Mo 10O 38H 4] 6-, were found to serve as O 2-evolving catalysts in a system consisting of tris(2,2′-bipyridine)ruthenium(ii) (Ru(bpy) 3 2+) and sodium persulfate (S 2O2-8) in an aqueous borate buffer solution at pH 8.0. Kinetics of O 2 evolution reveals that the higher cobalt nuclearity is not necessary to attain the highly active nature of the catalyst.
AB - The Mo-based polyoxometalates containing mono- and dicobalt(iii) catalyst cores, [CoMo 6O 24H 6] 3- and [Co 2Mo 10O 38H 4] 6-, were found to serve as O 2-evolving catalysts in a system consisting of tris(2,2′-bipyridine)ruthenium(ii) (Ru(bpy) 3 2+) and sodium persulfate (S 2O2-8) in an aqueous borate buffer solution at pH 8.0. Kinetics of O 2 evolution reveals that the higher cobalt nuclearity is not necessary to attain the highly active nature of the catalyst.
UR - http://www.scopus.com/inward/record.url?scp=84856682455&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84856682455&partnerID=8YFLogxK
U2 - 10.1039/c2cc16821a
DO - 10.1039/c2cc16821a
M3 - Article
C2 - 22186698
AN - SCOPUS:84856682455
VL - 48
SP - 1653
EP - 1655
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 11
ER -