Well-defined triflylamide-tethered Arene-Ru(Tsdpen) complexes for catalytic asymmetric hydrogenation of ketones

Masato Ito, Yoshinori Endo, Takao Ikariya

研究成果: Contribution to journalArticle査読

50 被引用数 (Scopus)

抄録

Well-defined triflylamide-tethered arene-Ru(Tsdpen) complexes have been developed as highly efficient catalysts for the asymmetric hydrogenation of ketones, in which the suitable carbon chain length of the tether is responsible for the activation of H2 as well as the stereochemical outcome of the reaction. The asymmetric hydrogenation of aromatic ketones with the tethered complex with a C4 side chain gave the corresponding secondary alcohols with 91-98% ee, while the shorter congeners with a C2 or C3 side chain provided unsatisfactory results in terms of reactivity and selectivity.

本文言語英語
ページ(範囲)6053-6055
ページ数3
ジャーナルOrganometallics
27
23
DOI
出版ステータス出版済み - 12 8 2008
外部発表はい

All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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