Wide control of proton conductivity in porous coordination polymers

Akihito Shigematsu, Teppei Yamada, Hiroshi Kitagawa

研究成果: Contribution to journalArticle査読

399 被引用数 (Scopus)

抄録

The proton conductivities of the porous coordination polymers M(OH)(bdc-R) [H2bdc = 1,4-benzenedicarboxylic acid; M = Al, Fe; R = H, NH 2, OH, (COOH)2] were investigated under humid conditions. Good correlations among pKa, proton conductivity, and activation energy were observed. Fe(OH)(bdc-(COOH)2), having carboxy group and the lowest pKa, showed the highest proton conductivity and the lowest activation energy in this system. This is the first example in which proton conductivity has been widely controlled by substitution of ligand functional groups in an isostructural series.

本文言語英語
ページ(範囲)2034-2036
ページ数3
ジャーナルJournal of the American Chemical Society
133
7
DOI
出版ステータス出版済み - 2 23 2011
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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