X-ray absorption spectral studies on stoichiometric analysis of amphiphilic ruthenium (II) polypyridine complex on a poly(methyl methacrylate) film

Shuji Matsuo, Takashi Nakano, Sunao Yamada, Taku Matsuo, Hisanobu Wakita

    研究成果: Contribution to journalArticle査読

    2 被引用数 (Scopus)

    抄録

    An ultrathin poly(methyl methacrylate) film incorporating an amphiphilic ruthenium (II) polypyridine complex with long chain tails was prepared on a water surface by a casting-on-water method. X ray absorption spectroscopy were performed for various films prepared and references using the total electron yield method. Molar ratios between ruthenium head group and perchlorate ions at the solvent-water interface were found far from stoichiometric value (1:2) when the thin film was formed on fresh water.

    本文言語英語
    ページ(範囲)193-197
    ページ数5
    ジャーナルJournal of Electron Spectroscopy and Related Phenomena
    113
    2-3
    DOI
    出版ステータス出版済み - 2 2001

    All Science Journal Classification (ASJC) codes

    • 電子材料、光学材料、および磁性材料
    • 放射線
    • 原子分子物理学および光学
    • 凝縮系物理学
    • 分光学
    • 物理化学および理論化学

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